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Sunavalon Daphne X EARTH Link 2 [ PlantLinkEffect ] ATK 0 DEF - 2 Plant monsters This card cannot be targeted for attacks, but does not prevent your opponent from attacking you directly

it gains ATK equal to its Link Rating x 1000 until the end of this turn, also if it attacks a Defense Position monster this turn, inflict piercing battle damage to your opponent

It gains 3000 ATK

Effects that trigger in combat before damage calculation, like Valero, are of course also unblockable and are removed before the effect is used

Its that simple

(2) If this card you control would be used as material for the Synchro Summon of a Psychic monster, you can treat it as a non-Tuner